Organic Communications Articles
Issue: 4 October-December
Year: 2009 Volume: 2 Issue:4 October-December
1) Utility of cyclohexanethiols in organic synthesis
Publications on the preparations of cyclohexanethiols and its reactions are reviewed for the first time.Keywords Cyclohexanethiols disulphides displacement reactions DETAILS PDF OF ARTICLE © 2009 ACG Publications. All rights reserved.
2) Synthesis, spectral and antimicrobial activity of [3-(4-chloro-phenoxy)-2,4-diisopropyl)-2,3,4,5-tetrahydro-1H-3l5-benzo[e][1,3,2]diazaphosphepin-3-ylidene]-alkyl-amine (Staudinger reaction)
3-(4-chlorophenoxy)-2,4-diisopropyl-2,3,4,5-tetrahydro-1H-benzo[e][1,3,2]diaza-phosphepine was synthesized starting from 1,2-bis(bromomethyl)benzene by reacting with 2 equimolar isopropyl amine, one equimolar PBr3 and then one equimolar 4-chlorophenol, respectively. The Staudinger reaction of the diazaphphosphine with a series of alkyl azides gave the corresponding iminophosphoranes. Antibacterial activities of the synthesized iminophosphoranes were screenedKeywords Iminophosphoranes 1 2-bis(bromomethyl)benzene Isopropylamine phosphorus tribromide 4-chlorophenol alkyl azides DETAILS PDF OF ARTICLE © 2009 ACG Publications. All rights reserved.