JOURNAL 796


Organic Communications
VOLUME & ISSUE
Year: 2017 Issue: 1 January-March
PAGES
p.11 - 14
STATISTICS
Viewed 1397 times.
AUTHORS
    Shoko Yamamoto and Yutaka Okada
PDF OF ARTICLE

GRAPHICAL ABSTRACT


ABSTRACT


The oxidation reaction of ferrocene derivatives is important because of its biological applications. The reactivity is affected by metal ions. However, it is not clear how to interact the metal ions with the ferrocenes. In this paper, the oxidation reactivity of (o-acetylphenyl)ferrocene was investigated in the view of solvent effect and the addition effect of salicylic acid. Furthermore, the measurement of the relaxation time was carried out. As a result, Al 3+ would strongly interact with (o-acetylphenyl)ferrocene so that prevent the mobility of the acetyl group.

KEYWORDS
  • Ferrocene derivatives
  • metal ion
  • oxidation reaction
  • solvent effect
  • relaxation time
  • salicylic acid